Carbon Disulfide from Sulfur Dioxide and Charcoal
نویسندگان
چکیده
منابع مشابه
Oxidation of reduced sulfur species: carbon disulfide.
A detailed chemical kinetic model for oxidation of CS2 has been developed, on the basis of ab initio calculations for key reactions, including CS2 + O2 and CS + O2, and data from literature. The mechanism has been evaluated against experimental results from static reactors, flow reactors, and shock tubes. The CS2 + O2 reaction forms OCS + SO, with the lowest energy path involving crossing from ...
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A Sc NHC complex readily activates three equivalents of CO2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS2 is also activated by the labile carbenes, no metal involvement is observed.
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1958
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.61.935